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Dehydration System  


Features

  • By using UBE's polyimide membrane, it
    is possible to supply the feed vapor with the temperature of 120°C (248°C)
    and the pressure of 2 barg (28 psig) for example. The partial pressure of
    water vapor at the feed side is so high that no extremely high vacuum at the
    permeate side is required to secure the necessary driving force for dehydration.
  • No serious fouling problem occurs on
    the membrane surface because the feed is a clean vapor; not a liquid with
    contaminants. It brings an advantage of higher durability regarding the membrane
    performance.
  • Simple and compact unit, easy startup
    and shutdown operation and easy maintenance can improve the overall process
    economics. 

 

Applicable solvent or material
The dehydration for almost all kinds of organic solvents or materials is possible except phenols and acetoaldehyde. Especially preferable solvents are alcohols, esters and ethers.



Applicable process
The basic flowdiagram of the vapor separation process is as follows. It depends on the state of feed materials, however, the vapor with the increased pressure such as 1 to 2 barg (14 to 28 psig) is the most preferable in terms of the process economics.

1. Combination of membrane separation with distillation process or some other process

  • When concentrating a solvent-water mixture up to the content of the solvent as high as 99.5% in weight, a combined process is economically preferable, that is, up to 80% by using a distillation process and up to 99.5% followed by the membrane process. Especially it is most economical in case of treating an azeotrope mixture with water.
  • When raising the capacity of existing distillation column, there is no need to install a new bigger column because the decreased reflux operation is possible by adding a suitable membrane separation unit.
  • Reaction processes involving dehydration such as esterification.
  • Other processes requiring dehydration. 



Module Performance
UBE has two kinds of testing equipment, lab. scale and pilot scale, in order to obtain the design information for the customer's objective including multicomponents. The photograph shows our pilot scale unit using a commercial sized membrane module. Typical performance of this unit are as follows:

AIcohol/water Alcohol content in
Supply wt%
Alcohol content in
Product wt%
Supply quantity
kg/hr (Ib/H)
Ethanol 94 99.8 90 (198)
Isopropylalcohol 93 99.5 80 (176)