Category: Gas Separation with Membrane Technology >

CO2 Separation Membrane  data sheet


Membrane Separation Process
Membrane Separation performs on the principle of selective gas permeation. When gas mixture is introduced to the membrane, gas component dissolves into membrane material and diffuses through the membrane material. Solubility and diffusivity are different from gas component. Carbon dioxide, water vapor and hydrogen sulfide are easy permeable gas components, while methane, ethane and other hydrocarbons are very slow to permeate. This is why water and sour gas components in the natural gas are removed with the membrane. The driving force of gas separation is partial pressure difference of specific gas component between both sides of membrane.

 

How UBE Membrane Work
Our membrane is a hollow membrane made of aromatic polyimide. When a gas mixture is introduced to the outer side of hollow membrane at a pressure and the pressure of the other side of the membrane is maintained at a lower pressure, easy permeable gas components like CO2, H2O and H2S permeate through the membrane, while gas components like hydrocarbons are remained in the outer side of the membrane.

Membrane Module for CO2 Separation
We provide four types of membrane module for CO2 separation for commercial use.

Dimentions
Max. Press. (psig)
8ind x 160inl
2200
8ind x 80inl
2200
4ind x 160inl
2200
4ind x 80inl
2200
Durability Against Contaminants
Our membrane's compatibility against typical contaminants are summarized in the following Table.

Contaminants
Max. allowable content
Water vapor
Up to saturated
H2S
3 vol%
NH3 & Amines
100 vppm
Methanol
5 vol%
Methyl Ether
5 vol%
Benzene
1 vol%
Toluene
2000 vppm
C5 + Hydrocarbons
Up to saturated

Features of CO2 Membrane System

  1. Long lifetime of the membrane
    UBE's polyimide membrane is made of aromatic polyimide which is a strong material against compaction caused by CO2, H2S and hydrocarbons under high pressure. Also, because of high thermal resistance of polyimide, our membrane can be operated up to 100 °C. By applying higher operation temperature compaction can be minimized, also once declined permeability can be recovered.

  2. Compact & Simple System
    Because of high permeation flux and thin hollow fiber technology, our Membrane System applies only 1/2 to 1/4 membrane modules compared to the conventional relevant systems. Therefore our Membrane System is the most compact among available membrane systems. Also, because of excellent durability against contaminants, our Membrane System requires only a simple pretreatment.

  3. Applicable to CO2 rich gas
    Because of chemical & mechanical stability in sour gas treatment, our membrane is the most reliable one in CO2 separation from CO2 rich gas as EOR (Enhanced Oil Recovery).

  4. H2O and H2S can be removed
    Water vapor and hydrogen sulfide are easy permeable gas components, accordingly our Membrane System requires no additional facility as glycol unit and H2S adsorber to get sales gas satisfies pipeline specification.

  5. Excellent selectivity
    Our excellent selective membrane can minimize hydrocarbon loss and recycle gas volume in multistage treatment.

Performance Benefit

  1. Low Capital Investment 
    Our Membrane System is low in cost compared with other alternatives.

  2. Compact and easy Installation 
    Our Membrane System is a skid mounted with all necessary equipment and materials. Because of the largest permeability of CO2 and simplest pretreatment facility, our Membrane System is the most compact and the lightest in weight compared with other alternatives.

  3. Easy Operation
    Our Membrane System is the simplest one, and therefore start up and shut down is almost instant as introducing process gas in a pipeline.

  4. Maintenance Free
    Long lifetime of our membrane and no moving part in the System promises maintenance free operation.

  5. Flexibility
    Our Membrane System can be operated in a flexible operation range: 30 - 100%, also the capacity of the System can be easily expanded by installing additional membrane modules.

  6. High Reliability 
    Our Membrane's durability and our excellent design capability ensure high reliability of our Membrane System.

Applications
Our CO2 Membrane System is applied ranging from a small wellhead to a large scale installation.

  1. Natural gas treatment to satisfy pipeline specifications.

  2. CO2 for EOR (Enhanced Oil Recovery) injection.

  3. Integration with absorption process.

  4. Debottleneck an existing absorption plant.

  5. Landfill gas/Biogas upgrading.